Linked from
The 13 pages that link to Germanium, each with the reason it gives.
Dmitri MendeleevBroader topic: Its properties matched Mendeleev's predicted eka-silicon.
Periodic lawBroader topic: Its discovery provided another striking test of periodic prediction.
Point-Contact TransistorRelated: The first working devices used a germanium crystal.
Leo EsakiRelated: Esaki’s first tunneling diode experiments used heavily doped germanium.