Linked from

The 19 pages that link to Kinetic isotope effect, each with the reason it gives.

• Transition stateRelated: Its magnitude can reveal whether an isotopically substituted bond changes in the transition state.

• Arrhenius equationRelated: Isotope-dependent rates can reveal changes in effective activation parameters beyond a simple fit.

• Reaction mechanismRelated: Isotope-dependent rates can reveal whether a bond is made or broken in a key step.

• Heavy waterRelated: Deuterium’s extra mass makes reactions involving heavy water proceed differently.

• Reaction intermediateRelated: Rate changes can indicate whether bond breaking near an intermediate-forming step limits the reaction.

• Concerted reactionRelated: Isotope effects can reveal whether a bond to the substituted atom changes in the rate-limiting step.

• Elementary reactionRelated: Isotope-dependent rates can reveal which bond changes in a rate-limiting elementary step.

• Eyring equationRelated: Temperature-dependent isotope effects can probe transition-state structure and dynamics.

• Physical organic chemistryRelated: Isotope-dependent rates reveal whether particular bonds are formed or broken in a rate-limiting step.

• Rate-determining stepRelated: A substantial isotope effect can indicate that bond motion contributes to the controlling barrier.

• Hammond's postulateRelated: Isotope effects can reveal which bonds are changing in a transition state inferred using the postulate.

• Entropy of activationRelated: Temperature-dependent isotope effects can help distinguish entropic from enthalpic contributions to a barrier.

• Haloform reactionRelated: Alpha-hydrogen removal can influence the rate of the repeated halogenation steps.

• Pre-exponential factorRelated: Isotope-dependent prefactors can reveal changes in molecular motion and pathway.

• Activated complexRelated: Rate changes can reveal whether isotope-bearing bonds are altered in the activated complex.